The Effects of Copper Oxides on the Curing Behaviors of Bismaleimide Triazine Prepreg

The effect of copper oxides on the curing behaviors of the bismaleimide triazine (BT) prepreg is studied with infrared spectroscopy (IR), attenuated total reflection infrared spectroscopy (ATR), and X‐ray photoelectron spectroscopy (XPS). The result of IR analyses indicates that there is a concentration distribution present in the prepreg surface layer and the outer surface layer contains less cyanate, imide, and epoxide but more triazine groups than the inner layer. From ATR, it is concluded that the cuprous oxide attracts more cyanate ester resins but less bismaleimide resins from the prepreg to its surface than the cupric oxide. The copper surface affects the curing extent of the BT resin in contact and the cupric oxide has a more pronounced effect than the cuprous oxide, and this surface effect can extend to at least two microns deep into the BT prepreg from the contacted interface. The XPS results confirm that the BT/CuO interface contains more thermally stable and polar functional groups than the BT/Cu2O interface, and both two copper oxides attract only a small amount of brominated epoxy resin onto their surfaces. These results are attributed to the difference in preferential adsorptions and catalytic curing effects of two copper oxides on the BT prepreg in contact. The intensity changes of IR bands obtained from BT prepreg during cure. magnified image The intensity changes of IR bands obtained from BT prepreg during cure.