Recent experimental and theoretical studies of the nature of transport and disorder in the high-temperature fiuorite-structured halides is reviewed. The bulk of the information suggests that the anion motion in these systems consists of discrete jumps rather than a cooperative liquid-like diffusion. Although it is now clear that anions do not appreciably occupy the cube-centre interstitial sites the exact extent of the disorder has still to be resolved.
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A. V. Chadwick (1983) studied this question.
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