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May 1, 1998Chemistry Letters

RhCl(PPh3)3/NaI Catalyst System for Hydrosilylation of 1-Alkynes: Stereodivergent Syntheses of E- and Z-Alkenylsilanes with Heteroatom Substituents on Silicon

Atsunori Mori Eisuke Takahisa Hiroshi Kajiro Kazunori Hirabayashi Yasushi Nishihara Tamejiro Hiyama

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Abstract

Both (E)- and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.

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Mori et al. (1998) studied this question.

synapsesocial.com/papers/6a9f8d87accb0daecaf7e475 https://doi.org/10.1246/cl.1998.443

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