April 3, 1998Angewandte Chemie International Edition

Alkaline Earth Diazapentadienyl Compounds: Structure of [Ba2{(C6H11)NC(Me)CHC(Me)N(C6H11)}3{(SiMe3)2N}]

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Abstract

Three different bonding modes in one molecule! The diazapentadienyl ligands in the title compound 1 adopt η1,η1-N,N-chelating plus η5-terminal, η1η1-N,N chelating plus η5-bridging, and novel η1-N plus η3-1-aza-allyl bonding modes. R=cyclohexyl.

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Cite This Study

Clegg et al. (1998) studied this question.

synapsesocial.com/papers/6a9fa148db9a251fcf8d3907 https://doi.org/10.1002/(sici)1521-3773(19980403)37:6<796::aid-anie796>3.0.co;2-b

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