A macrocycle-linked polymer architecture that involves thiophene linkages between the phthalocyanine rings (see picture) has been found to have conductivities three orders of magnitude higher than previously investigated macrocycle-linked materials. Rigid three-dimensional iptycene scaffolds were used to prevent aggregation of the macrocycles, and yield highly soluble monomers with a cleft around the axial coordination sites of the metal center.
No takes yet. Share an insight, caveat, or question.
Kingsborough et al. (2000) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: