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Amide-functionalized NJU-Bai45 exhibits high volumetric and gravimetric CH 4 working capacities of 190 cm 3 cm –3 and 298 cm 3 g –1 (from 5.8 to 65 bar), higher than that of the similar NJU-Bai43 (187 cm 3 cm –3 and 292 cm 3 g –1 ). This finding indicates that nitrogen-functionalized aromatic ring may not always play a positive role in amide-MOF for CH 4 storage.
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Zhang et al. (2019) studied this question.
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