Kinetic isotope effects of atom-transfer reactions and their temperature dependences at high temperatures have been calculated for various hydrogen-atom–formaldehyde reactions. In the case of the “abstracting atom” kinetic isotope effect, a negative temperature coefficient is predicted in the high-temperature limit. The theoretical calculations are compared with experimental results in the literature and satisfactory agreement is obtained.
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Macdonald et al. (1968) studied this question.
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