A series of rhenium(I) surfactant complexes, fac -[Re(CO) 3 (N−N)(L)]PF 6 (N−N = diimine, L = pyridyl ligand), with various azo- and stilbene-containing ligands have been synthesized and their photophysical properties studied. The X-ray crystal structure of the complex fac -[Re(CO) 3 (bpy)(L)]PF 6 (bpy = 2,2‘-bipyridine, L = 4-(4‘-octadecyloxyphenylstyryl)pyridine) has been determined. The photoinduced isomerization processes of these complexes and their free ligands have been studied by electronic absorption and 1 H NMR spectroscopy, and their quantum yields determined.
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Yam et al. (2001) studied this question.
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