Addition of phenyllithium and methyllithium to tetracarbonyl[2-(phenyl-κC2‘),pyridine-κN]rhenium(I), 1, affords novel anionic acyl species that result from selective nucleophilic addition at the axial carbonyl ligand of the chelated Re(CO)4 species.
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Djukic et al. (1998) studied this question.
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