On-surface synthesis of tetracyanobenzene molecules with Mn atoms is presented. From metal-organic coordination networks at room temperature, Mn-phthalocyanines and finally small domains of polymeric Mn-phthalocyanines are formed upon annealing on the Ag(111) surface. Step-by-step on-surface reaction is studied in situ by scanning tunnelling microscopy under ultra-high vacuum.
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Koudia et al. (2014) studied this question.
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