The 1 S 0 level in the 5 p 4 ground configuration of Xe III has been revised. Parameter values for the 5 p 4 configuration have been determined by parametric fitting and the eigenvectors used to calculate transition probabilities for magnetic dipole as well as electric quadrupole transitions within the 5 p 4 configuration. An improved value for the ionization potential of Xe II is used to determine the energies of the 4 d 10 5 s 2 5 p 4 1 D 2 - 4 d 9 5 s 2 5 p 6 2 D 5/2 ( N 5 O 2,3 O 2,3 ( 1 D 2 )) and 4 d 10 5 s 5 p 5 1 P 1 -4 d 9 5 s 2 5 p 6 2 D 5/2 ( N 5 O 1 O 2,3 ( 1 P 1 )) Auger transitions in Xe, which are commonly used as reference lines in photoelectron spectroscopy.
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Hansen et al. (1982) studied this question.