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SO it goes: A straightforward method for the deoxygenation of sulfoxides based on iron catalysts is presented. Excellent performance is demonstrated by a system composed of [Fe2(CO)9] as catalyst and polymethylhydrosiloxane (PMHS) or PhSiH3 as reducing reagent under non-inert conditions. The outstanding applicability of this procedure is shown in the reduction of various substrates with excellent yields and good functional-group tolerance.
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Stephan Enthaler (2011) studied this question.
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