January 1, 1985Journal of the Chemical Society Chemical Communications

Metal atom synthesis and photochemistry of bis(η-pentamethylcyclopentadienyl)-tungsten dihydride

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Authors

FCF. Geoffrey N. ClokeUniversity of Sussex JGJennifer C. GreenUniversity of Oxford MGMalcolm L. H. GreenScience Oxford

Abstract

Cocondensation of tungsten vapour with 1,2,3,4,5-pentamethylcyclopentadiene gives bis(η-pentamethylcyclopentadienyl)tungsten dihydride, (η-C5Me5)2WH2; photolysis of the dihydride yields, sequentially, the ‘tucked-in’ compounds (η-C5Me5)W(η-C5Me4CH2)H and (η-C5Me5)W(η-C5Me3CH2CH2).

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Cite This Study

Cloke et al. (1985) studied this question.

synapsesocial.com/papers/6a9fcd5716360f1e481de48c https://doi.org/10.1039/c39850000945

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