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September 8, 2026AIChE JournalOpen Access

Microwave‐assisted co‐conversion of waste plastic and CO 2 to syngas over reconstructed ZnO – Fe 3 C / SiC

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Authors

HJHan JiZZZelan ZhuYZYuanbiao Zhao

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Overview

Catalytic study demonstrates microwave-assisted conversion of waste plastics and carbon dioxide into syngas over reconstructed catalysts, highlighting a sustainable path for plastic valorization.

Key Points

  • To develop a microwave-driven catalytic process that simultaneously upcycles waste plastics and utilizes carbon dioxide to produce sustainable syngas.
  • Employed microwave irradiation to drive the reaction between polyethylene and carbon dioxide over a ZnFe2O4/SiC catalyst precursor.
  • Facilitated and monitored the in situ structural reconstruction of ZnFe2O4/SiC into active ZnO–Fe3C/SiC during the catalytic reaction.
  • Silicon carbide converted microwave radiation directly into heat, accelerating the decomposition of polyethylene into hydrogen and carbon intermediates.
  • Fe3C functioned as a dynamic carbon reservoir while zinc oxide dissociated carbon dioxide into carbon monoxide and oxygen species.
  • Reactive oxygen species coupled with Fe3C-bound carbon to generate additional carbon monoxide, enabling in situ carbon removal and catalyst self-stabilization.

Cite This Study

Ji et al. (2026) studied this question.

synapsesocial.com/papers/6a9fd7c658e84d0ff5b46d0ahttps://doi.org/10.1002/aic.70631
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