The natural product 4-(4-methoxyphenethyl)-cyclohex-2-en-1-one (1) isolated from the liverwort Plagiochila longispina was synthesised in four steps using a zeolite β induced 1,4-rearrangement of an allylic PMBO-ether as a key reaction.
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Wennerberg et al. (1997) studied this question.
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