The thermal decomposition of t‐butylmethyl ether has been studied using the VLPP technique. The recommended Arrhenius parameters for the molecular elimination, reaction (1), are A(800°K) = 101 3, 9 sec−1 and Ea (800°K) = 59.0 ± 1.0 kcal/mole. No radical reactions occur under the conditions used. magnified image These parameters are in good agreement with earlier experimental work and with theoretical estimates of both A and E.
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Choo et al. (1974) studied this question.
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