Rates of adsorption and desorption, of di-isopropyldithiophosphoric acid and tetraisopropylthioperoxydiphosphate from hexade-cane on to steel, have been measured wing 14C radiolabelled compounds. Concentration, temperature, and stirring dependence have been examined. The adsorption is surface controlled and the kinetics can be represented by a Langmuir model. Correlation of rate data with antiwear properties is examined.
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Bovington et al. (1984) studied this question.
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