Surface-reduced Si-doped TiO2 nanotubes for high-efficiency photoelectrochemical water splitting

This is the authors' abstract. We don't add key points for this paper.

TiO2 is a promising photocatalyst in the reaction of water splitting for hydrogen. Here, we used NaBH4 reduction reaction to introduce [Formula: see text]/VO defect states into Si-doped TiO2 nanotubes and investigated the photoelectrochemical water splitting properties. It was found that the photocatalytic activity was improved through NaBH4 reduction because of the existence of [Formula: see text]/VO. The defect states ([Formula: see text]/VO) could play a role of capture trap and accelerate the separation of photogenerated electrons and holes. The photocurrent density of the Si-doped TiO2 nanotubes reduced for 3[Formula: see text]h was 1.5[Formula: see text]mA/cm2 compared to 0.7[Formula: see text]mA/cm2 of the unreduced nanotubes. The conversion efficiency was 0.7%, which was almost 4 times than that of pure TiO2. On the other hand, reduction for a long time would generate excess defect states and thus cause the decrease of photocurrent density. Excess defect states could act as the recombination centers of photogenerated electrons and holes.