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February 26, 2008Angewandte Chemie

Enantioselective O‐Nitroso Aldol Reaction of Silyl Enol Ethers

Masanori Kawasaki Pingfan Li Hisashi Yamamoto

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Abstract

Neue Nucleophile – die leicht zugänglichen Disilanylenolether – sorgen für bequemere und vielseitigere O-Nitroso-Aldolreaktionen. Ein Silberkatalysator mit einem chiralen Biarylphosphitliganden vermittelt die hoch enantio- und regioselektive Titelreaktion (siehe Schema). R1,R2 = H, Ar; TMS = Trimethylsilyl.

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Kawasaki et al. (2008) studied this question.

synapsesocial.com/papers/6a9ff1c4b709eacd8e71e50e https://doi.org/10.1002/ange.200705679

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