December 1, 1997Organometallics

Phosphinoalkylsilyl Complexes. 12. Stereochemistry of the Tridentate Bis(diphenylphosphinopropyl)silyl (biPSi) Framework: Complexation That Introduces “Face Discrimination” at Coordinatively Unsaturated Metal Centers. X-ray Crystal and Molecular Structures of PtSiMe(CH2CH2CH2PPh2)2Cl, IrHSiMe(CH2CH2CH2PPh2)2Cl, and RuHSiMe(CH2CH2CH2PPh2)2(CO)21

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Brost et al. (1997) studied this question.

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