The novel title compound {NiII4MoV12} demonstrates the concept of generating targeted spin topologies using reduced polyoxometalates: The four electrophilic nickel centersforming a tetrahedronare fixed by a nucleophilic highly reduced diamagnetic ε-Keggin cluster of Td symmetry generated in solution. This cluster not only has a structural role but actually participates in the transmission of the exchange interaction.
No takes yet. Share an insight, caveat, or question.
Müller et al. (2000) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: