The photoelectron spectrum of nitric monoxide NO has been studied with the 73.58 nm line of Ne I. Strong perturbation of theX1Σ+anda3Σ+bands is ascribed to autoionisation from a Rydberg state. The molecular characteristics of the R-state are discussed on the basis of selection rules, comparison between experimental vibrational progressions and Franck-Condon factors calculations, and a2Σ+symmetry is deduced. Electronic branching ratios are also examined.
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Natalis et al. (1977) studied this question.
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