The absorption spectrum of CHF3 in a free jet expansion has been recorded at a resolution of 0·004 cm-1 in the 8–9 μm region. The line width is found to be essentially Doppler limited. An approximate rotational temperature of 40K has been determined from the spectrum. Relative intensities and transition moments for the interacting bands are discussed.
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Amrein et al. (1987) studied this question.
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