Abstract 1-(ω-Alkenyl)-1,2-propadienyl sulfide reacts with Fe(CO)4(NMe3) under photo irradiation conditions and a cyclized and carbonylated η3-allyl mononuclear iron complex is isolated. On the other hand, the reaction of 1-(ω-alkynyl)-1,2-propadienyl sulfides and Fe(CO)4(NMe3) also proceeds by photo irradiation to give various bicyclic dienones through the η3-allyl iron complex.
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Narasaka et al. (1994) studied this question.
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