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A slippery character: Cyclooligomerization of resorcinol with a highly fluorinated aldehyde afforded a “teflon-footed” resorcinarene 1F, which is soluble in wet fluorous solvents through formation of a hexameric capsule. The supramolecular capsules in fluorous solvents exhibited more selective and/or enhanced properties as a result of fluorophobic effects on molecular encapsulation (such as encapsulating eight molecules of benzene, see picture).
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Shimizu et al. (2007) studied this question.
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