The syntheses of [(CS(CH3}S}2Mn]PF6' (CS(CH3}S}2Mn, and Na [(C S (CH 3 ) S'2Mn] c are described.Magnetic susceptibility, infrared, electrochemical, NMR, and reactivity studies suggest the formulation of these complexes as low spin 16-, 17-, and 18electron planar metallocences.EPR spectra of the neutral complex are consistent with the 2 E2g configuration determined for other low spin l7-electron metallocenes.
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Robbins et al. (1979) studied this question.