The drop size distribution of vinyl chloride in water emulsions has been studied using a photographic technique. A large difference in coalescence stability was observed between emulsions stabilized by a poly(vinyl alcohol), Rhodoviol 5/270, and those stabilized by a cellulose ether, Methocel MF50. Experiments simulating the transport of a monomer soluble initiator to the monomer phase of a coalescence stable vinyl chloride in water emulsion showed that the manner of introducing the initiator may have large consequences on the polymerization process.
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Nilsson et al. (1985) studied this question.
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