An alkyl‐Heck‐type cross‐coupling reaction is developed by manganese‐catalyzed oxidative decarbonylation of aldehydes. A variety of primary, secondary, and tertiary aliphatic aldehydes can participate in this alkenylation. The reaction is initiated by an alkyl radical, which is generated by oxidative decarbonylation of the aldehyde.
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Zong et al. (2015) studied this question.
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