A novel self-assembly multilayer film was fabricated from fullerenol (C 60 (ONa) n ) and diazoresin (DR) a photosensitive polymer on indium-tin-oxide substrate. The film shows good stability after UV irradiation and has photoelectric conversion property, which can be measured in a conventional photoelectrochemical cell. The cathodal photocurrent was measured to be about 800 nA/cm 2 for a nine-layer film at 100 mW/cm 2 white light. The photocurrent spectroscopy responses coincide with the absorption spectrum of the self-assembly film, which means that the C 60 (ONa) n /DR film is responsible for the photocurrent generation.
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Cao et al. (2001) studied this question.
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