The potential of mean force is calculated for one ion immersed in a fluid of dipolar hard spheres in the vicinity of a neutral hard wall. The molecular nature of the solvent induces significant deviations from the primitive model result. A pure MSA treatment would only give the potential of mean force associated with the hard sphere fluid. The present theory automatically includes the existence of the image potential.
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Badiali et al. (1985) studied this question.
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