Electron Transport in Quasi‐Two‐Dimensional Porous Network of Titania Nanoparticles, Incorporating Electrical and Optical Advantages in Dye‐Sensitized Solar Cells

The integration of fast electron transport and large effective surface area is critical to attaining higher gains in the nanostructured photovoltaic devices. Here, we report facilitated electron transport in the quasi‐two‐dimensional (Q2D) porous TiO2. Liquid electrolyte dye‐sensitized solar cells were prepared by utilizing photoanodes based on the Q2D porous substructures. Due to electron confinement in a microscale porous medium, directional diffusion toward collecting electrode is induced into the electron transport. Our measurements based on the photocurrent and photovoltage time‐of‐flight transients show that at higher Fermi levels, the electron diffusion coefficient in the Q2D porous TiO2 is about one order of magnitude higher when compared with the conventional layer of porous TiO2. The results show that microstructuring of the porous TiO2 leads to an approximately threefold improvement in the electron diffusion length. Such a modification may considerably affects the electrical functionality of moderate or low performance dye‐sensitized solar cells for which the internal gain or collection efficiency is typically low.