[reaction: see text] 3,3'-Dimethyl-2,2'-diamino-1,1'-binaphthyl (DM-DABN) is designed as a "chiral poison" (deactivator) for complete enantiomer resolution of racemic BINAP-Ru(II) catalysts in a highly enantioselective hydrogenation of beta-keto ester and kinetic resolution of racemic 2-cyclohexen-1-ol.
No takes yet. Share an insight, caveat, or question.
Mikami et al. (2002) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: