The wall‐jet ring‐disc electrode: The measurement of homogeneous rate constants from steady state ring currents

The wall‐jet ring‐disc electrode is shown to provide a convenient means determining homogeneous rate constants by means of ring current measurements as a function of disc currents and electrolyte flow rates. Theory is provided for the analysis of such “collection efficiency” experiments and applied to the specific case of the bromination of anisole, where good agreement with experiment is found. Advantages with respect to the rotating ring‐disc electrode are pointed out.