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Langmuir-Hinshelwood-Hougen-Watson rate expressions are developed for the hydroprocessing of quinoline, naphthalene and dibenzothiophene based on batch reactor data at 350°C and at 500 psig. Based on competitive adsorption, the kinetics are extended to binary mixtures of quinoline/naphtha-lene and quinoline/dibenzothiophene. In doing so, the differences in hydrogenation and hydro-genolysis sites are taken into consideration. In all cases, the agreement between the predicted and experimental results are good
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Sundaram et al. (1988) studied this question.
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