A novel chitosan‐based adsorbent (CCTE) was synthesized by the reaction between epichlorohydrin O‐cross‐linked chitosan and EDTA dianhydride under microwave irradiation (MW). The chemical structure of this new polymer was characterized by infrared spectra analysis, thermogravimetric analysis, and X‐ray diffraction analysis. The results were in agreement with the expectations. The static adsorption properties of the polymer for Pb2+, Cu2+, Cd2+, Ni2+, and Co2+ were investigated. Experimental results demonstrated that the CCTE had higher adsorption capacity for the same metal ion than the parent chitosan and cross‐linked chitosan. In particular, the adsorption capacities for Pb2+ and Cd2+ were 1.28 mmol/g and 1.29 mmol/g, respectively, in contrast to only 0.372 mmol/g for Pb2+ and 0.503 mmol/g for Cd2+ on chitosan. Kinetic experiments indicated that the adsorption of CCTE for the above metal ions achieved the equilibrium within 4 h. The desorption efficiencies of the metal ions on CCTE were over 93%. Therefore, CCTE is an effective adsorbent for the removal and recovery of heavy metal ions from industrial waste solutions.
No takes yet. Share an insight, caveat, or question.
Ge et al. (2009) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: