Through hydride or fluoride abstraction, the dication 1 reacts with BH3 · THF (PF) to give monocationic complexes in which a hydrido (fluoro) ligand bridges a WW triple bond (WW single bond). The unusually high electrophilicity of 1 arises from the combination of positive charge and metal–metal multiple bond. The counterion in each case is PF6.
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Alvarez et al. (1993) studied this question.
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