The binding energy of oxygen on Pd nanoparticles was measured by a direct calorimetric method as a function of the particle size. The reduced dimensionality of the Pd substrate results in two counteracting trends: an increase of the PdO binding strength due to a change of the local configuration of the adsorption site and a strong decrease of the PdO bonding due to the reduction of the cluster size.
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Peter et al. (2013) studied this question.
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