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Thermal and photolytic decompositions of azobis(2-phenylthio)-2-propane have been studied. The reaction mechanisms have been discussed on the basis of products. Almost all reactions of 2-phenylthioprop-2-yl radicals produced from the azo compound photolytically proceed with in-cage processes. The ratio, disproportionation/dimerization, predicts qualitatively that the radical center of the free radical is more electronegative than that of the corresponding oxygen analog.
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Ohno et al. (1971) studied this question.
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