Velocity structure in optical CH(+) lines toward HD 190603 and implications for the formation of CH(+)

Observations of CH(+) and other species accessible in optical wavelengths in the line of sight to HD 190603, a B 1.5 Iae supergiant are reported. In this line of sight a shift in radial velocity between the CH(+) line and other interstellar absorption lines such as CH and Ca I is observed. The most likely explanation for this effect is the shock formation of CH(+). Likely preshock and postshock conditions which are consistent with the observations are also estimated.