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Significant theoretical and experimental advances during the past three years in the area of equilibrium isotope effects are reviewed. Section headings are: isotope separation; chemical exchange equilibria: theory; calculations of reduced partition function ratios; chemical exchange equilibria: experimental; solvent isotope effects; isotope effects in phase equilibria; and physical properties of a substance upon isotopic substitution, including heat capacity, phase transitions, superconductivity, and crystalline structure. (248 references) (auth)
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Bigeleisen et al. (1973) studied this question.
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