The molecular structures of monocyclic sulfur‐nitrogen ring systems, such as S2N2, S3N , S4N and S5N , can be considered as examples of electron rich (4n + 2)π systems. The structures of S4N4, S4N , P4S4, As4S4 and the bicyclic structures S4N , S4N as well as S5N6 can be rationalized on the basis of a planar tetrasulfur tetranitride with 12π electrons.
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Rolf Gleiter (1981) studied this question.
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