NiL2 and PdL2 are the first metal dioximates possessing layered polymer structures. Such packing leads to an effective exchange interaction between N·−O groups through the diamagnetic metal ion. The increase in the M−O·− distance decreases the superexchange in the N·−O···M···O·−N exchange clusters.
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Овчаренко et al. (1998) studied this question.
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