The general aspects of polymerization of diene monomers included in the crystal lattice of suitable hosts are discussed. Particular attention has been devoted to the behavior of adducts formed by perhydrotriphenylene. Study of the phase diagrams revealed a strict correlation between stability and reactivity in the solid state. Some recent results, concerning inclusion copolymerization and production of polymers with unusual steric structure (e.g., hemitactic polypropylene), are reported.
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Farina et al. (1983) studied this question.
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