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November 4, 2003Organometallics

Formation of Phosphirenes by Phosphinidene Group-Transfer Reactions from (dtbpe)NiP(dmp) to Alkynes

Rory Waterman Gregory L. Hillhouse

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Abstract

The nickel phosphinidene complex (dtbpe)NiP(dmp) (1) has been found to undergo a general reaction with alkynes to produce phosphirenes. For PhC⋮CH, the olefin-bound nickel−phosphirene adduct (dtbpe)Ni{η2(C,C)-cyclo-CHC(Ph)P(dmp)} (2) has been isolated and crystallographically characterized.

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Waterman et al. (2003) studied this question.

synapsesocial.com/papers/6aa1664cf432c06896ac7d7f https://doi.org/10.1021/om0341754

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