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M12L24 spherical complexes incorporating 24 free pyridine rings on their interior or exterior surfaces were synthesized via the self-assembly of tridentate tris(pyridine) ligands with Pd(2+) ions. Coordination of secondary metal ions in the interior of the spherical framework was achieved through interactions of 24 Ag(+) ions with the free endo pyridine rings.
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Harris et al. (2013) studied this question.
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