A minor species, generated by CH activation of the methyl group of CH3ReO3 on reactive surface sites of alumina, is the active site of alumina-supported CH3ReO3, a highly active olefin metathesis catalyst, while the major species, formed by coordination of CH3ReO3 at the same sites, is inactive (see scheme; Os denotes the O atoms of the alumina surface).
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Salameh et al. (2007) studied this question.
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