New click chemistry is demonstrated. Click polymerization proceeded via 1,3-dipolar polycycloaddition of homo-ditopic nitrile oxides to bifunctional terminal olefinic and acetylenic monomers as dipolarophiles. Molecular sieves (MS 4A) served as an efficient promoter for the polymerization to afford polyisoxazolines and polyisoxazoles in high yields.
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Koyama et al. (2008) studied this question.
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