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). The introduction of Co into the Ni-MOF matrix shortens Co/Ni-centered bond distances, resulting in improved bond strength, facilitating the charge transfer and increasing the electrical conductivity of the CoNi-MOF, which were proved by X-ray absorption fine structure (XAFS) spectroscopy, high angle annular dark field (HAADF) imaging, and electrochemical impedance spectroscopy (EIS). Our study demonstrates the origin of performance improvements and, therefore, may provide a feasible scheme to unlock high-performance MOF electrode materials.
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Chu et al. (2020) studied this question.
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