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The transesterification reaction of dialkyl and diaryl phosphites with triethanolamine, N‐methyldiethanolamine and diethanolamine was examined. The transesterification process with aminoalcohols begins at considerably lower temperatures than that with aliphatic diols. A probable mechanism of the transesterification of dialkyl and diaryl phosphites with amino alcohols is suggested. Phosphorus‐containing polyurethanes are obtained by using N,N‐diethanolaminoethyl phosphite.
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Troev et al. (1985) studied this question.
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