Detection of the Ammonium Ion in Space

We report on the detection of a narrow feature at 262816.73 MHz toward Orion and the cold prestellar core B1-bS which we attribute to the 1 0 –0 0 line of the deuterated ammonium ion, NH 3 D + . The observations were performed with the IRAM 30 m radio telescope. The carrier has to be a light molecular species as it is the only feature detected over 3.6 GHz of bandwidth. The hyperfine structure is not resolved, indicating a very low value for the electric quadrupolar coupling constant of nitrogen which is expected for NH 3 D + as the electric field over the N nucleus is practically zero. Moreover, the feature is right at the predicted frequency for the 1 0 –0 0 transition of the ammonium ion, 262817 ± 6 MHz (3σ), using rotational constants derived from new infrared data obtained in our laboratory in Madrid. The estimated column density is (1.1 ± 0.2) × 10 12 cm −2 . Assuming a deuterium enhancement similar to that of NH 2 D, we derive N (NH ) ≃ 2.6 × 10 13 cm −2 , i.e., an abundance for ammonium of a few 10 −11 .